p17
Section 1.1 Being macroscopic---why do we need statistics?
Conceptual
-
*`Macroscopic,’ and `equilibrium’
-
*Partition/reconstruction invariance of thermodynamic observables
We must pay due attention to the nature and characteristics of thermodynamic observables (esp., the zeroth and the fourth laws; however, without the first and the second laws we cannot really specify what a thermodynamic state is).
-
*Statistics in statistical mechanics does not describe the `true’ statistics of the states actually realized in a macroscopic equilibrium system. Statistics is a `trick’ or `filter’ to extract thermodynamic observables from microscopic mechanical description of the system.
Technical
*Homogeneous functions and Euler’s theorem, Gibbs-Duhem relation
*Precise definition of ergodicity; it is a property of a measure-theoretical dynamical system.